A Sol-Gel Modified Alternative Nafion-Silica Composite Membrane for Polymer Electrolyte Fuel Cells

Mechanical Properties of Nafion and Titania/Nafion Composite Membranes for Polymer Electrolyte Membrane Fuel Cells

Measurements of the mechanical and electrical properties of Nafion and Nafion/titania composite membranes in constrained environments are reported. The elastic and plastic deformation of Nafion-based materials decreases with both the temperature and water content. Nafion/titania composites have slightly higher elastic moduli. The composite membranes exhibit less strain hardening than Nafion. Co...

Metallic plate corrosion and uptake of corrosion products by nafion in polymer electrolyte membrane fuel cells.

Nafion contamination by ferrous-alloy corrosion products, resulting in dramatic drops of the Ohmic potential, is a suspected major failure mode of polymer electrolyte membrane fuel cells that make use of metallic bipolar plates. This study demonstrates the potential of scanning transmission X-ray microscopy combined with X-ray absorption and fluorescence microspectroscopy for exploring corrosio...

Immobilization of Glucose Oxidase/ferrocene Carboxylic Acid in Composite Silica Sol-gel/cross-linked Poly (vinyl Alcohol)/nafion Membrane

A method of tethering a mediator to an enzymatic membrane was studied to construct a non-leaking mediated glucose biosensor. Ferrocene carboxylic acid and glucose oxidase were immobilized in a sol gel derived silica (SGS) matrix containing cross-linked poly (vinyl alcohol) (CLPVA) and Nafion. CLPVA was applied as a solid support due to the ability to form very homogenous films with high quality...

Proton Conductivity of Graphene-based Nafion® Catalyst Layer for Polymer Electrolyte Membrane Fuel Cell

Nafion Nanofiber Composite Membrane Fabrication for Fuel Cell Applications

A proton exchange membrane has been developed for direct methanol fuel cell (DMFC). The nanofiber network composite membranes were prepared by interconnected network of Nafion (perfuorosulfonic acid) nanofibers that have been embedded in an uncharged and inert polymer matrix, by electro-spinning. The spinning solution of Nafion with a low concentration (1 wt% compared to Nafion) of high molecul...